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synthesis and evaluation of (s)prolinecontaining α,β ...内容提示: Asymmetric SynthesisSynthesis and Evaluation of (S)ProlineContaining a,bDipeptidesas Organocatalysts in SolventFree Asymmetric Aldol ReactionsUnder BallMilling ... the organocatalytic activity of three prolinebased a,bdipeptides was evaluated in the asymmetricaldol reaction between cyclohexanone and 4 ...
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Tetrahedron Letters (, #32) | An efficient procedure for transesterification has been developed in a ballmill in the absence of any solvent, acid/base or metal catalyst. A variety of methyl, ethyl, allyl esters have been transesterified to higher benzyl and other esters in high yields by this procedure.
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prolinamide Publications | PubFactsThese Lprolinamidefunctionalized hollow nanospheres are highly efficient solid catalysts for the direct asymmetric aldol reaction between cyclohexanone and aromatic aldehydes. Read More. View Article. July 2010. ... Key Laboratory of Green Chemistry Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064 ...
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Water versus Solventfree Conditions for the ...Water versus Solventfree Conditions for the Enantioselective Inter and Intramolecular Aldol Reaction Employing LProlinamides and L ... Aldol reaction / Asymmetric organocatalysis / Water / Solventfree reactions / Prolinethioamides ... efficacy of catalyst 1d was similar when the reaction was performed in a ball mill[9a,9b] (Table 1, entry ...
Dr Eusebio Juaristi Areas de Investigacion RELAQ(3) Hernández y E. Juaristi, "Efficient BallMill Procedure in the "Green" Asymmetric Aldol Reaction Organocatalyzed by (S)ProlineContaining Dipeptides in the Presence of Water", Tetrahedron, 67, (2011).
ball milling asymmetric organocatalysis Efficient ballmill procedure in the green asymmetric aldol reaction ... ball details milling Asymmetric organocatalysis in a ball mill – Beilstein In the laboratory the ball milling device is shown, and reaction details are revealed.
SYNTHESIS « New Drug ApprovalsIn general, the intermolecular asymmetric aldol reaction has been shown to perform poorly in pure aqueous media and is typically performed in organic solvents such as DMF, DMSO, etc. However, structural modifications to l proline and 4hydroxy l proline have generated catalysts capable of asymmetric aldol reactions in aqueous media.
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